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J. Chem. Thermodynamics 27: 707–20. © 2002 by CRC Press LLC Chapter 4 DECOMPOSITION CHEMISTRY OF HIGH-ENERGY-DENSITY FUELS BY FLOW TUBE MASS SPECTROMETRY Z. Li and S. L. Anderson A method is described that allows study of thermal breakdown behavior of organic high-energy-density fuel molecules. In addition to stability vs. temperature results, the distribution of product species as a function of temperature is also determined. The method uses a microflow tube reactor to allow study of small samples.

18. Marchand, A. , I. N. N. Namboothiri, B. Ganguly, and S. G. Bott. 1998. Study of a vinylidenecarbene–cycloalkyne equilibrium in the D3-trishomocubyl ring system. J. American Chemical Society 120:6871–76. 19. Marchand, A. , Y. Wang, S. Alihodzic, and D. H. R. Barton. 1997. 010,14 ]tetradecane (HCTD)8. Tetrahedron 53:1257–64. 20. , D. -D. Martin, B. Mayer, T. J. Chow, A. P. -T. Ren, and M. N. Paddon-Row. 1991. 010,14 ]tetradecane system. Chemisches Berichte 124:2871–78. 21. Chow, T. -J. -J. -K.

32. Stine, J. R. 1981. Prediction of crystal densities of organic explosives by group additivity. Report LA-8920. Los Alamos National Laboratory, Los Alamos, NM. 33. Choi, C. , and E. Prince. 1972. The crystal structure of cyclotrimethylenetrinitramine. Acta Crystallographica, Sect. B B28:2857–62. 34. Cady, H. , A. C. Larson, and D. T. Cromer. 1963. The crystal structure of α-HMX and a refinement of the structure of β-HMX. Acta Crystallographica 16:617–23. 35. Zhitomirskaya, N. , N. T. Erernko, N.

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Advances in Chemical Propulsion (auth unkn) [No TOC]


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